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Concept — what does that mean?

Wave–particle duality

Both radiation and matter show wave behaviour in some experiments and particle behaviour in others.

In Swedish: Våg–partikeldualism

What it is

Wave–particle duality means that the same object, light or an electron, gives results like a wave in some experiments and like a particle in others. Neither classical picture is enough by itself.

For light:

For matter it is the other way round. Particles have a wavelength, de Broglie’s hypothesis: λ = h/p = h/(mv); see de Broglie wavelength.

What is not duality:

Why it matters

Duality is the doorway to quantum physics. Because a particle has a wavelength, position and momentum cannot both be given exactly; see the Heisenberg uncertainty principle. A particle trapped in a box is allowed only certain wavelengths and so only certain energies; see particle in a box. The electron microscope works because electron waves have a much shorter wavelength than visible light and so resolve more detail.

Common misconceptions

Common questions

What is de Broglie’s hypothesis? That every particle with momentum p has a wavelength λ = h/p. It was confirmed when electrons produced interference off crystals.

Why can’t we see a ball behave like a wave? Its wavelength is around 10⁻³⁴ m, far smaller than an atomic nucleus, and no experiment can detect it.

Which experiments show the wave side and the particle side? Interference and diffraction show the wave. The photoelectric effect and Compton scattering show the particle; see Compton scattering.

Work functions of metals

Table

Work functions of metals
Metalφ (eV)φ (J)λ₀ (nm)
CaesiumCs1.953.12 × 10⁻¹⁹636
RubidiumRb2.053.28 × 10⁻¹⁹605
PotassiumK2.303.69 × 10⁻¹⁹539
SodiumNa2.363.78 × 10⁻¹⁹525
BariumBa2.524.04 × 10⁻¹⁹492
CalciumCa2.874.6 × 10⁻¹⁹432
ZincZn3.635.82 × 10⁻¹⁹342
LeadPb4.256.81 × 10⁻¹⁹292
SilverAg4.266.83 × 10⁻¹⁹291
AluminiumAl4.286.86 × 10⁻¹⁹290
TinSn4.286.86 × 10⁻¹⁹290
TitaniumTi4.336.94 × 10⁻¹⁹286
ChromiumCr4.447.11 × 10⁻¹⁹279
MolybdenumMo4.497.19 × 10⁻¹⁹276
TungstenW4.557.29 × 10⁻¹⁹272
IronFe4.607.37 × 10⁻¹⁹270
CopperCu4.657.45 × 10⁻¹⁹267
GoldAu5.108.17 × 10⁻¹⁹243
NickelNi5.158.25 × 10⁻¹⁹241
PlatinumPt5.639.02 × 10⁻¹⁹220

Sources

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Last reviewed October 20, 2026 ·How pages are reviewed

Modern physicsAll formulas